Extraction–Pyrolytic Method for TiO2 Polymorphs Production
نویسندگان
چکیده
The unique properties and numerous applications of nanocrystalline titanium dioxide (TiO2) are stimulating research on improving the existing developing new synthesis methods. In this work, we demonstrate for first time possibilities extraction–pyrolytic method (EPM) production TiO2 powders. A titanium-containing precursor (extract) was prepared by liquid–liquid extraction using valeric acid C4H9COOH without diluent as an extractant. Simultaneous thermogravimetric analysis differential scanning calorimetry (TGA–DSC), well Fourier-transform infrared (FTIR) spectroscopy were used to determine temperature conditions fabricate powders free organic impurities. produced materials also characterized X-ray diffraction (XRD) transmission electron microscopy (TEM). results showed possibility fabrication storage-stable liquid (IV)-containing precursor, which provided It established that EPM permits both monophase (anatase polymorph or rutile polymorph) biphase (mixed anatase–rutile polymorphs), impurity-free For comparison, precipitation method. presented in study could serve a solid basis further cheap simple TiO2-based form doped powders, thin films, composite materials.
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ژورنال
عنوان ژورنال: Crystals
سال: 2021
ISSN: ['2073-4352']
DOI: https://doi.org/10.3390/cryst11040431